Search for toe straightening socks and you will find plenty of promises. Realign your toes. Correct your bunion. Reverse years of damage while you sleep. Most of it is overstated, and it is worth being clear about that before we talk about what actually helps.
Here is the honest version. Toes drift out of position over years, usually from narrow shoes, sometimes from genetics, arthritis, or the way you walk. That drift involves bone, joint capsule, and soft tissue. A sock does not undo it.
What a sock can do is hold your toes in a spread, uncrowded position for hours at a time instead of a squeezed one, and NeuroSox five-toe socks do that with a separate pocket for every toe. For people with crowded, overlapping, or rubbing toes, that is often the difference between an uncomfortable day and a comfortable one.

What toe crowding does over time
Modern shoes taper. Almost all of them, including most athletic shoes. Your foot is widest at the toes, and your shoe is narrowest there. Spend forty years in that shape and your toes adapt to it, drifting inward, sometimes overlapping, sometimes curling.
The visible results are bunions, hammer toes, corns between toes, and calluses on the sides of the big and little toe. The invisible result is that your foot loses some of its natural ability to spread and grip the ground.
What separation actually accomplishes
Three real things, none of them miraculous.
It stops skin-on-skin friction, which is the source of most between-toe corns and soreness.
It lets your foot spread under load, which is how a foot is designed to work and which many people find gives them a more stable feeling when standing.
It gives your toes hours in a neutral position instead of a compressed one, which tends to feel good in the same way stretching feels good, without claiming to permanently change anything.
Sock versus toe spacer
Rigid silicone toe spacers push toes apart more aggressively. They are effective for short sessions and uncomfortable for long ones, and you generally cannot walk around in them.
A five-toe sock is gentler and you can wear it all day, in shoes, doing normal things. The grip sole means moving around the house is not a hazard. Some people use both, spacers for a focused twenty minutes and socks for daily wear.
Set expectations honestly
If your toes are flexible and simply crowded from footwear, you will likely notice they feel and look more spread after regular wear, particularly right after taking the socks off. If your toes are rigid, arthritic, or have a fixed deformity, expect comfort rather than change in position. If a toe is painful, fixed, or getting worse, that is a podiatrist conversation, not a sock conversation.
We would rather tell you that up front than have you expect something a sock cannot deliver.